Tag Archives: Royal Society

Third time lucky

At the end of last year my research group had articles published by the Royal Society’s journal  Open Science in two successive months [see ‘Press Release!‘ on November 15th, 2017 and ‘Slow moving nanoparticles‘ on December 13th, 2017].  I was excited about both publications because I had only had one article published before by the Royal Society and because the Royal Society issues a press release whenever it publishes a new piece of science.  However, neither press release generated any interest from anyone; probably because science does not sell newspapers (or attract viewers) unless it is bad news or potentially life-changing.  And our work on residual stress around manufactured holes in aircraft or on the motion of nanoparticles does not match either of these criteria.

Last month, we did it again with an article on ‘An experimental study on the manufacture and characterization of in-plane fibre-waviness defects in composites‘.  Third time lucky, because this time our University press office were interested enough to write a piece for the news page of the University website, entitled ‘Engineers develop new method to recreate fibre waviness defects in lab‘.  Fibre waviness is an issue in the manufacture of structural components of aircraft using carbon fibre reinforced composites because kinks or waves in the fibres can cause structural weaknesses.  As part of his PhD, supported by Airbus and the UK Engineering and Physical Sciences Research Council (EPSRC), Will Christian developed an innovative technique to generate defects in our lab so that we can gain a better understanding of them. Read the article or the press release to find out more!

Image shows fracture through a waviness-defect in the top-ply of a carbon-fibre laminate observed in a microscope following sectioning after failure.


Christian WJR, DiazDelaO FA, Atherton K & Patterson EA, An experimental study on the manufacture and characterisation of in-plane fibre-waviness defects in composites, R. Soc. open sci. 5:180082, 2018.

Slow moving nanoparticles

Random track of a nanoparticle superimposed on its image generated in the microscope using a pin-hole and narrowband filter.

A couple of weeks ago I bragged about research from my group being included in a press release from the Royal Society [see post entitled ‘Press Release!‘ on November 15th, 2017].  I hate to be boring but it’s happened again.  Some research that we have been performing with the European Union’s Joint Research Centre in Ispra [see my post entitled ‘Toxic nanoparticles‘ on November 13th, 2013] has been published this morning by the Royal Society Open Science.

Our experimental measurements of the free motion of small nanoparticles in a fluid have shown that they move slower than expected.  At low concentrations, unexpectedly large groups of molecules in the form of nanoparticles up to 150-300nm in diameter behave more like an individual molecule than a particle.  Our experiments support predictions from computer simulations by other researchers, which suggest that at low concentrations the motion of small nanoparticles in a fluid might be dominated by van der Waals forces rather the thermal motion of the surrounding molecules.  At the nanoscale there is still much that we do not understand and so these findings will have potential implications for predicting nanoparticle transport, for instance in drug delivery [e.g., via the nasal passage to the central nervous system], and for understanding enhanced heat transfer in nanofluids, which is important in designing systems such as cooling for electronics, solar collectors and nuclear reactors.

Our article’s title is ‘Transition from fractional to classical Stokes-Einstein behaviour in simple fluids‘ which does not reveal much unless you are familiar with the behaviour of particles and molecules.  So, here’s a quick explanation: Robert Brown gave his name to the motion of particles suspended in a fluid after reporting the random motion or diffusion of pollen particles in water in 1828.  In 1906, Einstein postulated that the motion of a suspended particle is generated by the thermal motion of the surrounding fluid molecules.  While Stokes law relates the drag force on the particle to its size and fluid viscosity.  Hence, the Brownian motion of a particle can be described by the combined Stokes-Einstein relationship.  However, at the molecular scale, the motion of individual molecules in a fluid is dominated by van der Waals forces, which results in the size of the molecule being unimportant and the diffusion of the molecule being inversely proportional to a fractional power of the fluid viscosity; hence the term fractional Stokes-Einstein behaviour.  Nanoparticles that approach the size of large molecules are not visible in an optical microscope and so we have tracked them using a special technique based on imaging their shadow [see my post ‘Seeing the invisible‘ on October 29th, 2014].


Coglitore D, Edwardson SP, Macko P, Patterson EA, Whelan MP, Transition from fractional to classical Stokes-Einstein behaviour in simple fluids, Royal Society Open Science, 4:170507, 2017. doi:

Press release!

A jumbo jet has about six million parts of which roughly half are fasteners – that’s a lot of holes.

It is very rare for one of my research papers to be included in a press release on its publication.  But that’s what has happened this month as a consequence of a paper being included in the latest series published by the Royal Society.  The contents of the paper are not earth shattering in terms of their consequences for humanity; however, we have resolved a long-standing controversy about why cracks grow from small holes in structures [see post entitled ‘Alan Arnold Griffith‘ on  April 26th, 2017] that are meant to be protected from such events by beneficial residual stresses around the hole.  This is important for aircraft structures since a civilian airliner can have millions of holes that contain rivets and bolts which hold the structure together.

We have used mechanical tests to assess fatigue life, thermoelastic stress analysis to measure stress distributions [see post entitled ‘Counting photons to measure stress‘ on November 18th, 2015], synchrotron x-ray diffraction to evaluate residual stress inside the metal and microscopy to examine failure surfaces [see post entitled ‘Forensic engineering‘ on July 22nd, 2015].  The data from this diverse set of experiments is integrated in the paper to provide a mechanistic explanation of how cracks exploit imperfections in the beneficial residual stress field introduced by the manufacturing process and can be aided in their growth by occasional but modest overloads, which might occur during a difficult landing or take-off.

The success of this research is particularly satisfying because at its heart is a PhD student supported by a dual PhD programme between the University of Liverpool and National Tsing Hua University in Taiwan.  This programme, which supported by the two partner universities, is in its sixth year of operation with a steady state of about two dozen PhD students enrolled, who divide their time between Liverpool, England and Hsinchu, Taiwan.  The synchrotron diffraction measurements were performed, with a colleague from Sheffield Hallam University, at the European Synchrotron Research Facility (ESRF) in Grenoble, France; thus making this a truly international collaboration.


Amjad K, Asquith D, Patterson EA, Sebastian CM & Wang WC, The interaction of fatigue cracks with a residual stress field using thermoelastic stress analysis and synchrotron x-ray diffraction experiments, R. Soc. Open Sci. 4:171100.

Alan Arnold Griffith

Everest of fracture surface [By Kaspar Kallip (CC BY-SA 4.0), via Wikimedia Commons]

Some of you maybe aware that I hold the AA Griffith Chair of Structural Materials and Mechanics at the University of Liverpool.  I feel that some comment on this blog about Griffith’s seminal work is long overdue and so I am correcting that this week.  I wrote this piece for a step in week 4 of a five-week MOOC on Understanding Super Structures which will start on May 22nd, 2017.

Alan Arnold Griffith was a pioneer in fracture mechanics who studied mechanical engineering at the University of Liverpool at the beginning of the last century.  He earned a Bachelor’s degree, a Master’s degree and a PhD before moving to work for the Royal Aircraft Establishment, Farnborough in 1915.

He is famous for his study of failure in materials.  He observed that there were microscopic cracks or flaws in materials that concentrated the stress.  And he postulated that these cracks were the source of failure in a material.  He used strain energy concepts to analyse the circumstances in which a crack or flaw would propagate and cause failure of a component.  In order to break open a material, we need to separate adjacent atoms from one another, and break the bonds between them.  This requires a steady supply of energy to do the work required to separate one pair of atoms after another and break their bonds.  It’s a bit like unpicking a seam to let out your trousers when you’ve put on some weight.  You have to unpick each stitch and if you stop working the seam stays half undone.  In a material with a stress raiser or concentration, then the concentration is quite good at delivering stress and strain to the local area to separate atoms and break bonds.  This is fine when external work is being applied to the material so that there is a constant supply of new energy that can be used to break bonds.  But what about, if the supply of external energy dries up, then can the crack continue to grow?  Griffith concluded that in certain circumstances it could continue to grow.

He arrived at this conclusion by postulating that the energy required to propagate the crack was the work of fracture per unit length of crack, that’s the work needed to separate two atoms and break their bond.  Since atoms are usually distributed uniformly in a material, this energy requirement increases linearly with the length of the crack.  However, as the crack grows the material in its wake can no longer sustain any load because the free surface formed by the crack cannot react against a load to satisfy Newton’s Law.  The material in the wake of the crack relaxes, and gives up strain energy [see my post entitled ‘Slow down time to think (about strain energy)‘ on March 8th, 2017], which can be used to break more bonds at the crack tip.  Griffith postulated that the material in the wake of the crack tip would look like the wake from a ship, in other words it would be triangular, and so the strain energy released would proportional to area of the wake, which in turn would be related to the crack length squared.

So, for a short crack, the energy requirement to extend the crack exceeds the strain energy released in its wake and the crack will be stable and stationary; but there is a critical crack length, at which the energy release is greater than the energy requirements, and the crack will grow spontaneously and rapidly leading to very sudden failure.

While I have followed James Gordon’s lucid explanation of Griffith’s theory and used a two-dimensional approach, Griffith actually did it in three-dimensions, using some challenging mathematics, and arrived at an expression for the critical length of crack. However, the conclusion is the same, that the critical length is related to the ratio of the work required for new surfaces and the stored strain energy released as the crack advances.  Griffith demonstrated his theory for glass and then others quickly demonstrated that it could be applied to a range of materials.

For instance, rubber can absorb a lot of strain energy and has a low work of fracture, so the critical crack length for spontaneous failure is very low, which is why balloons go pop when you stick a pin in them.  Nowadays, tyre blowouts are relatively rare because the rubber in a tyre is reinforced with steel cords that increase the work required to create new surfaces – it’s harder to separate the rubber because it’s held together by the cords.

By the way, James Gordon’s explanation of Griffith’s theory of fracture, which I mentioned, can be found in his seminal book: ‘Structures, or Why Things Don’t Fall Down’ published by Penguin Books Ltd in 1978.  The original work was published in the Proceedings of the Royal Society as ‘The Phenomena of Rupture and Flow in Solids’ by AA Griffith, February 26, 1920.