Tag Archives: experimental mechanics

Size matters

3 Replies

Most of us have a sub-conscious understanding of the forces that control the interaction of objects in the size scale in which we exist, i.e. from millimetres through to metres.  In this size scale gravitational and inertial forces dominate the interactions of bodies.  However, at the size scale that we cannot see, even when we use an optical microscope, the forces that the dominate the behaviour of objects interacting with one another are different.  There was a hint of this change in behaviour observed in our studies of the diffusion of nanoparticles [see ‘Slow moving nanoparticles‘ on December 13th, 2017], when we found that the movement of nanoparticles less than 100 nanometres in diameter was independent of their size.  Last month we published another article in one of the Nature journals, Scientific Reports, on ‘The influence of inter-particle forces on diffusion at the nanoscale‘, in which we have demonstrated by experiment that Van der Waals forces and electrostatic forces are the dominant forces at the nanoscale.  These forces control the diffusion of nanoparticles as well as surface adhesion, friction and colloid stability.  This finding is significant because the ionic strength of the medium in which the particles are moving will influence the strength of these forces and hence the behaviour of the nanopartices.  Since biological fluids contain ions, this will be important in understanding and predicting the behaviour of nanoparticles in biological applications where they might be used for drug delivery, or have a toxicological impact, depending on their composition.

Van der Waals forces are weak attractive forces between uncharged molecules that are distance dependent.  They are named after a Dutch physicist, Johannes Diderik van der Waals (1837-1923).  Electrostatic forces occur between charged particles or molecules and are usually repulsive with the result that van der Waals and electrostatic forces can balance each other, or not depending on the circumstances.

Sources:

Giorgi F, Coglitore D, Curran JM, Gilliland D, Macko P, Whelan M, Worth A & Patterson EA, The influence of inter-particle forces on diffusion at the nanoscale, Scientific Reports, 9:12689, 2019.

Coglitore D, Edwardson SP, Macko P, Patterson EA, Whelan MP, Transition from fractional to classical Stokes-Einstein behaviour in simple fluids, Royal Society Open Science, 4:170507, 2017. doi: 10.1098/rsos.170507.

Patterson EA & Whelan MP, Tracking nanoparticles in an optical microscope using caustics. Nanotechnology, 19 (10): 105502, 2009.

Image: from Giorgi et al 2019, figure 1 showing a photograph of a caustic (top) generated by a 50 nm gold nanoparticle in water taken with the optical microscope adjusted for Kohler illumination and closing the condenser field aperture to its minimum following method of Patterson and Whelan with its 2d random walk over a period of 3 seconds superimposed and a plot of the same walk (bottom).

Joining the dots

2 Replies

Six months ago, I wrote about ‘Finding DIMES’ as we kicked off a new EU-funded project to develop an integrated measurement system for identifying and tracking damage in aircraft structures.  We are already a quarter of the way through the project and we have a concept design for a modular measurement system based on commercial off-the-shelf components.  We started from the position of wanting our system to provide answers to four of the five questions that Farrar & Worden [1] posed for structural health monitoring systems in 2007; and, in addition to provide information to answer the fifth question.  The five questions are: Is there damage? Where is the damage? What kind of damage is present? How severe is the damage?  And, how much useful life remains?

During the last six months our problem definition has evolved through discussions with our EU Topic Manager, Airbus, to four objectives, namely: to quantify applied loads; to provide condition-led/predictive maintenance; to find indications of damage in composites of 6mm diameter or greater and in metal to detect cracks longer than 1mm; and to provide a digital solution.  At first glance there may not appear to be much connection between the initial problem definition and the current version; but actually, they are not very far apart although the current version is more specific.  This evolution from the idealised vision to the practical goal is normal in engineering projects.

We plan to use point sensors, such as resistance strain gauges or fibre Bragg gratings, to quantify applied loads and track usage history; while imaging sensors will allow us to measure strain fields that will provide information about the changing condition of the structure using the image decomposition techniques developed in previous EU-funded projects: ADVISE, VANESSA (see ‘Setting standards‘ on January 29th, 2014) and INSTRUCTIVE.  We will use these techniques to identify and track cracks in metals [2]; while for composites, we will apply a technique developed through an EPSRC iCASE award from 2012-16 on ‘Full-field strain-based methods for NDT & structural integrity measurement’ [3].

I gave a short briefing on DIMES to a group of Airbus engineers last month and it was good see some excitement in the room about the direction of the project.  And, it felt good to be highlighting how we are building on earlier investments in research by joining the dots to create a deployable measurement system and delivering the complete picture in terms of information about the condition of the structure.

Image: Infra red photograph of DIMES meeting in Ulm.

References

  1. Farrar & Worden, An introduction to structural health monitoring, Phil. Trans. R Soc A, 365:303-315, 2007
  2. Middleton, C.A., Gaio, A., Greene, R.J. & Patterson, E.A., Towards automated tracking of initiation and propagation of cracks in aluminium alloy coupons using thermoelastic stress analysis, Nondestructive Evaluation, 38:18, 2019.
  3. Christian, W.J.R., DiazDelaO, F.A. & Patterson, E.A., Strain-based damage assessment of accurate residual strength prediction of impacted composite laminates, Composites Structures, 184:1215-1223, 2018.

The INSTRUCTIVE and DIMES projects have received funding from the Clean Sky 2 Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreements No. 685777 and No. 820951 respectively.

The opinions expressed in this blog post reflect only the author’s view and the Clean Sky 2 Joint Undertaking is not responsible for any use that may be made of the information it contains.

Archive video footage from EU projects

2 Replies

This week I am in the US presenting work from our EU projects INSTRUCTIVE and MOTIVATE at the Annual Conference and Exposition of the Society for Experimental Mechanics.  Although the INSTRUCTIVE project was completed at the end of December 2018, the process of disseminating and exploiting the research will go on for some time.  The capability to identify the initiation of cracks when they are less than 1mm long and to track their propagation is a key piece of technology for DIMES project in which we are developing an integrated system for monitoring the condition of aircraft structures.  We are in the last twelve months of the MOTIVATE project and we have started producing video clips about the technology that is being developed.  So, if you missed my presentations at the conference in the US then you can watch the videos online using the links below 😉.

We have been making videos describing the outputs of our EU project for about 20 years; so, if you want to see some vintage footage of me twenty years younger then watch a video from the INDUCE project that was active from 1998 to 2001.

MOTIVATE videos: Introduction; Industrial calibration of DIC measurements using a calibration plate or using an LCD screen

The MOTIVATE project has received funding from the Clean Sky 2 Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreement No. 754660.

Image: Peppermill Hotel in Reno, Nevada where the conference is being held.

 

Assessing nanoparticle populations in historic nuclear waste

Leave a reply

Together with colleagues at the JRC Ispra, my research group has shown that the motion of small nanoparticles at low concentrations is independent of their size, density and material [1], [see ‘Slow moving nanoparticles‘ on December 13th, 2017].  This means that commercially-available instruments for evaluating the size and number of nanoparticles in a solution will give erroneous results under certain conditions.  In a proposed PhD project, we are planning to extend our work to develop an instrument with capability to automatically identify and size nanoparticles, in the range from 1 to 150 nanometres, using the three-dimensional optical signature, or caustic, which particles generate in an optical microscope, that can be several orders of magnitude larger than the particle [2],  [see ‘Toxic nanoparticles?‘ on November 13th, 2013].  The motivation for the work is the need to characterise particles present in solution in legacy ponds at Sellafield.  Legacy ponds at the Sellafield site have been used to store historic radioactive waste for decades and progress is being made in reducing the risks associated with these facilities [3].  Over time, there has been a deterioration in the condition of the ponds and their contents that has resulted in particles being present in solution in the ponds.  It is important to characterise these particles in order to facilitate reductions in the risks associated with the ponds.  We plan to use our existing facilities at the University of Liverpool to develop a novel instrument using simple solutions probably with gold nanoparticles and then to progress to non-radioactive simulants of the pond solutions.  The long-term goal will be to transition the technology to the Sellafield site perhaps with an intermediate step involving a demonstration of  the technology on pond solutions using the facilities of the National Nuclear Laboratory.

The PhD project is fully-funded for UK and EU citizens as part of a Centre for Doctoral Training and will involve a year of specialist training followed by three years of research.  For more information following this link.

References:

[1] Coglitore, D., Edwardson, S.P., Macko, P., Patterson, E.A., & Whelan, M.P., Transition from fractional to classical Stokes-Einstein behaviour in simple fluids, Royal Society Open Science, 4:170507, 2017.

[2] Patterson, E.A., Whelan, P., 2008, ‘Optical signatures of small nanoparticles in a conventional microscope’ Small, 4(10):1703-1706.

[3] Comptroller and Auditor General, The Nuclear Decommissioning Authority: progress with reducing risk at Sellafield, National Audit Office, HC 1126, Session 2017-19, 20 June 2018.