Category Archives: energy science

Electron uncertainty

daisyMost of us are uncomfortable with uncertainty.  Michael Faraday’s ability to ‘accept the given – certainties and uncertainties’ [see my post entitled ‘Steadiness and placidity’ on July 18th, 2016] was exceptional and perhaps is one reason he was able to make such outstanding contributions to science and engineering.  It has been said that his ‘Expts. on the production of Electricity from Magnetism, etc. etc.’ [Note 148 from Faraday’s notebooks] on August 29th 1831  began the age of electricity.  Electricity is associated with the flow of electric charge, which is often equated with the flow of electrons and electrons are subatomic particles with a negative elementary charge and a mass that is approximately 1/1836 atomic mass units.  A moving electron, and it is difficult to find a stationary one, has wave-particle duality – that is, it simultaneously has the characteristics of a particle and a wave.  So, there is uncertainty about the nature of an electron and most of us find this concept difficult to handle.

An electron is both matter and energy.  It is a particle in its materialisation as matter but a wave in its incarnation as energy.  However, this is probably too much of a reductionist description of a systemic phenomenon.  Nevertheless let’s stay with it for a moment, because it might help elucidate why the method of measurement employed in experiments with electrons influences whether our measurements reflect the behaviour of a particle or a wave.  Perhaps when we design our experiments from an energy perspective then electrons oblige by behaving as waves of energy and when we design from a matter perspective then electrons materialise as particles.

All of this leads to a pair of questions about what is matter and what is energy?  But, these are enormous questions, and even the Nobel Laureate Richard Feynman said ‘in physics today, we have no knowledge of what energy is’, so I’m going to leave them unanswered.  I’ve probably already riled enough physicists with my simplistic discussion.

Note: an atomic mass unit is also known as a Dalton and is equivalent to 1.66×10-27kg

Source:

Hamilton, J., A life of discovery: Michael Faraday, giant of the scientific revolution. New York: Random House, 2002.

Pielou EC, The Energy of Nature [the epilogue], Chicago: The University of Chicago Press, 2001.

Subtle balance of sustainable orderliness

129-2910_IMGI wrote this short essay a couple of weeks for another purpose and then changed my mind about using it.  So I thought I would share it on this blog.

Whenever we do something, some of our useful resource gets converted into productive activity but some is always lost in useless waste.  In other words, 100% efficiency is impossible – we can’t convert all of our resource into productive activity.  Engineers call this the second law of thermodynamics.  Thermodynamics is about energy transitions, for instance converting chemical energy in fossil fuels into electrical energy in a power station, and in these circumstances, the useless waste is called entropy.  At the time of the industrial revolution, Rudolf Clausius recognised that entropy can be related to the heat losses which occur whenever we do something useful, such as generating electricity in a power station, cleaning the house with an electric vacuum cleaner or running to catch the bus.

Clausius’s definition of entropy was really useful for designers of 19th century steam engines but it is difficult to use in other walks of life.  Fortunately Ludwig Boltzmann gave us a more valuable description.  He equated entropy to the number of states in which something could be arranged, or its lack of orderliness.  In other words, the more ways you can arrange something, the less ordered it is likely to be and the higher its entropy.  So a box of children’s building blocks has a low entropy when the blocks are packed in their box because there is a relatively small number of ways of arranging them to fit in the box.  When the box is emptied onto your living room floor, there are very many more possible arrangements and so the blocks have a high entropy.  The chance of knowing the whereabouts of a particular block is small. Whoops!  Now we’ve wondered into information theory.

Let’s get back to the second law, which using Boltzmann’s description of entropy, we can express as the level of orderliness should always decrease.  Stephen Hawking describes this as the arrow of time.  Because, if someone shows you a video clip in which steam gathers itself together and returns into a cup of coffee, or that box of children’s blocks repacks itself, then we know the video is being run backwards because these processes involve decreasing entropy and this can only happen spontaneously if we reverse the direction of time.  If this is true then why do we exist as highly ordered structures?

Erwin Schrödinger in his book, ‘What is Life’ says that organisms suck orderliness out of the environment in order to exist, so that the orderliness of the universe, that’s the organism and its environment, decreases.  Humans digest highly-ordered food to sustain life and food, in the form of plants, is brought into existence by metabolising energy from the sun and releasing entropy in the form of heat.  When we die these processes cease and the orderliness is sucked out of us to sustain insects, maggots and bacteria.

We are organisms, known as Sapiens, that organise ourselves into cultures and societies.  Organisation implies an increase in the level of orderliness in apparent contradiction of the second law.  So, we would expect to find a corresponding increase in disorder somewhere to counterbalance the order in society.  The more regimented society becomes the greater the requirement for counterbalancing disorder to occur somewhere in order to satisfy the second law, which might happen unexpectedly and explosively if the level of constraint or regulation is too great.  This is not an argument for anarchy or total deregulation, the financial sector has already demonstrated the risks associated with this path, but for an optimum and sustainable level of orderliness.  This requires subtle judgment just like in elegant engineering design and living a healthy life, both physically and psychologically.

Popping balloons

Balloons ready for popping

Balloons ripe for popping!

Each year in my thermodynamics class I have some fun popping balloons and talking about irreversibilities that occur in order to satisfy the second law of thermodynamics.  The popping balloon represents the unconstrained expansion of a gas and is one form of irreversibility.  Other irreversibilities, including friction and heat transfer, are discussed in the video clip on Entropy in our MOOC on Energy: Thermodynamics in Everyday Life which will rerun from October 3rd, 2016.

Last week I was in Florida at the Annual Conference of the Society for Experimental Mechanics (SEM) and Clive Siviour, in his JSA Young Investigator Lecture, used balloon popping to illustrate something completely different.  He was talking about the way high-speed photography allows us to see events that are invisible to the naked eye.  This is similar to the way a microscope reveals the form and structure of objects that are also invisible to the naked eye.  In other words, a high-speed camera allows us to observe events in the temporal domain and a microscope enables us to observe structure in the spatial domain.  Of course you can combine the two technologies together to observe the very small moving very fast, for instance blood flow in capillaries.

Clive’s lecture was on ‘Techniques for High Rate Properties of Polymers’ and of course balloons are polymers and experience high rates of deformation when popped.  He went on to talk about measuring properties of polymers and their application in objects as diverse as cycle helmets and mobile phones.

Entropy in poetry

WIN_20140716_190901 (2)Few weeks ago I mentioned about reading undergraduate dissertations [see my post entitled ‘A Startling Result‘ on May 18th, 2016] and about a year ago I wrote about the low quality of prose produced by engineers [see my post entitled ‘Reader, Reader, Reader‘ on April 15th, 2015 ].  Coleridge described prose as words in the best order and poetry as the best words in the best order. So today I’d like to direct you to a poem entitled ‘Entropy‘ by Neil Rollinson from his anthology ‘Spanish Fly’.  Here are a few lines from it:

“I open the window, the sky is dark
and the house is also cooling, the garden,
the summer lawn, all of it finding an equilibrium.”

I came across it while reading an anthology called ‘A Quark for Mister Mark: 101 Poems about Science‘ edited by Maurice Riordan and Jon Turney.  I was dipping into it while enjoying a pint in our backyard after a personal battle with entropy: painting rusting railings in our yard.

I was reviewing ‘A Quark for Mister Mark’ as potential reading material for a module on Technical Writing as part of our new CPD programme on Advanced Technical Skills.