Tag Archives: Thermodynamics

Will it all be over soon?

milkywayNASAAs you may have gathered from last week’s post [Man, the Rubbish-Maker on October 26th, 2016], I have been reading Italo Calvino’s Complete Cosmicomics.  In one story, ‘World Memory’ the director of a project to document the entire world memory in the ‘expectation of the imminent disappearance of life on Earth’ is explaining to his successor that ‘we have all been aware for some time that the Sun is halfway through its lifespan: however well things went, in four or five billion years everything would be over’.  The latter is one of the scientific conclusions around which Calvino weaves these short stories and this one put into perspective the concerns expressed by some of my students on both my undergraduate course and MOOC in thermodynamics the prospect of a cosmic heat death resulting from the inevitable consequences of the second law of thermodynamics [see my post ‘Cosmic Heat Death‘ on February 18th, 2015].  The second law requires ‘entropy of the universe to increase in all spontaneous processes’.   Entropy was defined by Rudolf Clausius about 160 years ago as the heat dissipated in a process divided by the temperature of the process.  The dissipated heat flows into random motion of molecules from which it is never recovered.  So, as William Thomson observed, this must eventually create a universe of uniform temperature – an equilibrium state corresponding to maximum entropy where nothing happens and life cannot exist.   Entropy has been increasing since the Big Bang about 13.5 billion years ago.  And as Calvino writes, the sun is about halfway through its life – it is expected to collapse into a white dwarf in 4 to 5 billion years when its supply of hydrogen runs out.  These are enormous timescales: the first human cultures appeared about 70,000 years ago [see my post ‘And then we discovered thermodynamics‘ on February 3rd, 2016]  and history would suggest that our civilization will disappear long before the sun expires or cosmic heat death occurs.  A more immediate existential threat is that our local production of entropy on Earth destroys the delicate balance of conditions that allows us to thrive on Earth.  See my post on Free Riders on April 6th, 2016 for thoughts on avoiding this threat.

Sources:

Italo Calvino, The Complete Cosmicomics, London: Penguin Books, 2002.

 

Revisiting closed systems in nature

milkywayNASA

It is the beginning of the academic year and once again I am teaching introductory thermodynamics to engineering undergraduate students and my MOOC entitled ‘Energy: Thermodynamics in Everyday Life‘ is running in parallel.  Last week after my lecture on thermodynamic systems, a student approached me to ask whether the universe is a closed and isolated system.  It’s an interesting question and the answer is depends on the definition of universe.   In thermodynamics, we usually define a boundary to delineate the system of interest as everything inside the boundary and everything else are the surroundings.  The system and surroundings taken together are the universe (see my post ‘No beginning or end‘ on February 24th, 2016).  If the universe is defined as the system then there are no surroundings; hence the system cannot exchange energy or matter with anything which is the definition of a closed and isolated system.

Physicists often refer to the observable universe, or define the universe as everything we can observe.  We are aware that we cannot observe everything.  Hence, it is reasonable to suppose that the observable universe exchanges energy and matter with the unobservable space beyond it, in which case the observable universe is an open system.  We could also consider the concept that we are part of multiverse and our universe is only one of many, in which case it seems likely that is not isolated, i.e. it can exchange energy, and perhaps it is open, i.e. it can exchange both energy and matter with other parts of the multiverse.

This is not really thermodynamics in everyday life.  However, the occurrence of closed systems in nature appears to interest a lot of people to judge from the visits to my previous posts on this topic.  See ‘Closed Systems in Nature?‘ on  December 12th, 2012; Is Earth a closed system? Does it matter? on December 10th, 2014; and ‘No Closed Systems in Nature‘ on August 12th, 2015. For more about system boundaries, see my post entitled ‘Drawing Boundaries‘ on December 19th, 2012.

Subtle balance of sustainable orderliness

129-2910_IMGI wrote this short essay a couple of weeks for another purpose and then changed my mind about using it.  So I thought I would share it on this blog.

Whenever we do something, some of our useful resource gets converted into productive activity but some is always lost in useless waste.  In other words, 100% efficiency is impossible – we can’t convert all of our resource into productive activity.  Engineers call this the second law of thermodynamics.  Thermodynamics is about energy transitions, for instance converting chemical energy in fossil fuels into electrical energy in a power station, and in these circumstances, the useless waste is called entropy.  At the time of the industrial revolution, Rudolf Clausius recognised that entropy can be related to the heat losses which occur whenever we do something useful, such as generating electricity in a power station, cleaning the house with an electric vacuum cleaner or running to catch the bus.

Clausius’s definition of entropy was really useful for designers of 19th century steam engines but it is difficult to use in other walks of life.  Fortunately Ludwig Boltzmann gave us a more valuable description.  He equated entropy to the number of states in which something could be arranged, or its lack of orderliness.  In other words, the more ways you can arrange something, the less ordered it is likely to be and the higher its entropy.  So a box of children’s building blocks has a low entropy when the blocks are packed in their box because there is a relatively small number of ways of arranging them to fit in the box.  When the box is emptied onto your living room floor, there are very many more possible arrangements and so the blocks have a high entropy.  The chance of knowing the whereabouts of a particular block is small. Whoops!  Now we’ve wondered into information theory.

Let’s get back to the second law, which using Boltzmann’s description of entropy, we can express as the level of orderliness should always decrease.  Stephen Hawking describes this as the arrow of time.  Because, if someone shows you a video clip in which steam gathers itself together and returns into a cup of coffee, or that box of children’s blocks repacks itself, then we know the video is being run backwards because these processes involve decreasing entropy and this can only happen spontaneously if we reverse the direction of time.  If this is true then why do we exist as highly ordered structures?

Erwin Schrödinger in his book, ‘What is Life’ says that organisms suck orderliness out of the environment in order to exist, so that the orderliness of the universe, that’s the organism and its environment, decreases.  Humans digest highly-ordered food to sustain life and food, in the form of plants, is brought into existence by metabolising energy from the sun and releasing entropy in the form of heat.  When we die these processes cease and the orderliness is sucked out of us to sustain insects, maggots and bacteria.

We are organisms, known as Sapiens, that organise ourselves into cultures and societies.  Organisation implies an increase in the level of orderliness in apparent contradiction of the second law.  So, we would expect to find a corresponding increase in disorder somewhere to counterbalance the order in society.  The more regimented society becomes the greater the requirement for counterbalancing disorder to occur somewhere in order to satisfy the second law, which might happen unexpectedly and explosively if the level of constraint or regulation is too great.  This is not an argument for anarchy or total deregulation, the financial sector has already demonstrated the risks associated with this path, but for an optimum and sustainable level of orderliness.  This requires subtle judgment just like in elegant engineering design and living a healthy life, both physically and psychologically.

Popping balloons

Balloons ready for popping

Balloons ripe for popping!

Each year in my thermodynamics class I have some fun popping balloons and talking about irreversibilities that occur in order to satisfy the second law of thermodynamics.  The popping balloon represents the unconstrained expansion of a gas and is one form of irreversibility.  Other irreversibilities, including friction and heat transfer, are discussed in the video clip on Entropy in our MOOC on Energy: Thermodynamics in Everyday Life which will rerun from October 3rd, 2016.

Last week I was in Florida at the Annual Conference of the Society for Experimental Mechanics (SEM) and Clive Siviour, in his JSA Young Investigator Lecture, used balloon popping to illustrate something completely different.  He was talking about the way high-speed photography allows us to see events that are invisible to the naked eye.  This is similar to the way a microscope reveals the form and structure of objects that are also invisible to the naked eye.  In other words, a high-speed camera allows us to observe events in the temporal domain and a microscope enables us to observe structure in the spatial domain.  Of course you can combine the two technologies together to observe the very small moving very fast, for instance blood flow in capillaries.

Clive’s lecture was on ‘Techniques for High Rate Properties of Polymers’ and of course balloons are polymers and experience high rates of deformation when popped.  He went on to talk about measuring properties of polymers and their application in objects as diverse as cycle helmets and mobile phones.