Tag Archives: Thermodynamics

Entropy and junkies

I am on a deep vacation [see ‘Digital detox with a deep vacation‘ on August 10th, 2016] and so my posts for the next few weeks will be ‘reprints’ from my archive of more than 570 posts.  The one below first appeared in January 2013 under the title ‘Unavoidable junk‘.

The laws of thermodynamics are physical laws whose relevance extend beyond the study of engines and heat plants. We can restate the first law of thermodynamics (conservation of energy) as ‘the quantity of matter is constant and finite’. Matter changes both in nature and as it moves through the economic system; and as it does so, its intrinsic properties change rendering it less useful and usable, thus requiring more and more resources to make it useful again. This last sentence is a form of the second law of thermodynamics. Very useful (low entropy) goods, such as iron ore and fossil fuels, eventually produce less useful (high entropy) matter, such as piles of junk cars in scrap-metal yards and greenhouse gases, as they move through the economic system. In our current western life-style, we are all contributing to the generation of vast piles of junk; we are hooked on it; we are all ‘junkies’.

In the paragraph above, I have plagiarised the 2009 report entitled ‘The New Sustainable Frontier’. However, similar ideas were expressed by Handscombe and Patterson in their 2004 book entitled the ‘Entropy Vector’. They paraphrased the first and second laws of thermodynamics as ‘you can’t have something nothing’ and ‘you can’t have it just anyway you like it’.

Storm in a computer

Decorative painting of a stormy seascapeAs part of my undergraduate course on thermodynamics [see ‘Change in focus’ on October 5th, 2022) and in my MOOC on Thermodynamics in Everyday Life [See ‘Engaging learners on-line‘ on May 25th, 2016], I used to ask students to read Chapter 1 ‘The Storm in the Computer’ from Philosophy and Simulation: The Emergence of Synthetic Reason by Manuel Delanda.  It is a mind-stretching read and I recommended that students read it at least twice in order to appreciate its messages.  To support their learning, I provided them with a précis of the chapter that is reproduced below in a slightly modified form.

At the start of the chapter, the simplest emergent properties, such as the temperature and pressure of a body of water in a container, are discussed [see ‘Emergent properties’ on September 16th, 2015].  These properties are described as emergent because they are not the property of a single component of the system, that is individual water molecules but are features of the system as a whole.  They arise from an objective averaging process for the billions of molecules of water in the container.  The discussion is extended to two bodies of water, one hot and one cold brought into contact within one another.  An average temperature will emerge with a redistribution of molecules to create a less ordered state.  The spontaneous flow of energy, as temperature differences cancel themselves, is identified as an important driver or capability, especially when the hot body is continually refreshed by a fire, for instance.  Engineers harness energy gradients or differences and the resultant energy flow to do useful work, for instance in turbines.

However, Delanda does not deviate to discuss how engineers exploit energy gradients.  Instead he identifies the spontaneous flow of molecules, as they self-organise across an energy gradient, as the driver of circulatory flows in the oceans and atmosphere, known as convection cells.  Five to eight convections cells can merge in the atmosphere to form a thunderstorm.  In thunderstorms, when the rising water vapour becomes rain, the phase transition from vapour to liquid releases latent heat or energy that helps sustain the storm system.  At the same time, gradients in electrical charge between the upper and lower sections of the storm generate lightening.

Delanda highlights that emergent properties can be established by elucidating the mechanisms that produce them at one scale and these emergent properties can become the components of a phenomenon at a much larger scale.  This allows scientists and engineers to construct models that take for granted the existence of emergent properties at one scale to explain behaviour at another, which is called ‘mechanism-independence’.  For example, it is unnecessary to model molecular movement to predict heat transfer.  These ideas allow simulations to replicate behaviour at the system level without the need for high-fidelity representations at all scales.  The art of modelling is the ability to decide what changes do, and what changes do not, make a difference, i.e., what to include and exclude.

Source:

Manuel Delanda Philosophy and Simulation: The Emergence of Synthetic Reason, Continuum, London, 2011.

Image: Painting by Sarah Evans owned by the author.

Change in focus

Decorative image of a painting by Sarah Evans The new academic year is well and truly underway.  It was 2019 when we last welcomed students to campus in person for the start of the academic year.  In my role as Dean, I have been touring lecture theatres trying to speak to and welcome students in all of our taught programmes in the School of Engineering.  It is exciting to see packed lecture theatres full of students eager to listen and learn.  For the first time in a decade, I am not teaching this year so that I can focus on other activities.  I have mixed feelings about giving up teaching.  I taught my first class thirty-six years ago in Mechanics of Solids.  For the last eleven years I have been teaching Thermodynamics to first year students [see, for example ‘From nozzles and diffusers to stars and stripes‘ on March 30th, 2022].  So, teaching has been a substantial part of my working life and its absence will leave a large hole.  I will miss the excitement of standing in front of a class of hundreds of students as well as the rewards of interacting with undergraduate students who are encountering and engaging with a new subject.  One consequence of my change in focus is likely to be a decline in the frequency of blog posts featuring thermodynamics [you can read them all under ‘Thermodynamics’ in Categories], but perhaps that will be a relief to many readers.

Image: Painting by Sarah Evans owned by the author.

Delaying cataclysmic events might hasten their advent

detail tl from abstract painting by Zahrah RIn thermodynamics, students are taught to draw a boundary around the system they want to analyse and to decide whether the boundary is open or closed to transfers of mass and energy based on the scenario they want to model.  The next step is to balance the energy flows across the boundary with the change in the energy content of the system.  This is an application of the first law of thermodynamics which is that energy can neither be created nor destroyed.  Rudolf Clausius is credited with discovering entropy when he realised that when energy flowed as heat across a system boundary it became entropy or disordered energy. For instance, when a steam engine does work and discharges heat to the environment. The second law of thermodynamics states that entropy of the universe increases in all real processes.  Thermodynamicists are not the only people who draw boundaries and decide whether they are open or closed.  Politicians and generals draw national boundaries occasionally and more frequently decide whether they are open or closed to people, goods and capital.  After the first world war economists, such as Friedrich Hayek and Ludwig von Mises, proposed that conflict would be less likely if people, goods and capital could flow freely across national boundaries.  These ideas became the principles on which the IMF and World Bank were formed at Bretton Woods in July 1944 in the closing stages of the second world war.  Presidents of the USA, since Ronald Reagan, have taken these ideas a step further by unleashing capitalism through deregulation of markets in the belief that markets know best.  However, ever-growing capital generates an ever-increasing rate of creation of entropy and disorder in the world [see ‘Existential connection between capitalism and entropy‘ on May 4th 2022] and perhaps attempting to reduce conflict by unfettering capital actually accelerates the descent into chaos and disorder because entropy increases in every transaction.

Sources:

Rana Foroohar, When the market fails us, FT Weekend, 23 April/24 April 2022.

Gary Gerstle, The Rise and Fall of the Neoliberal Order: America and the World in Free Market Era, Oxford: OUP, 2022.

The cataclysmic events referred to in the title are those identified by Thomas Piketty as being the only means by which economic inequality is reduced, i.e., wars and revolutions [see ‘Existential connection between capitalism and entropy‘ on May 4th 2022].  The title was inspired by correspondence from Bob Handscombe with whom I wrote a book entitled ‘The Entropy Vector: Connecting Science and Business‘.